BATTERYBatteries are provided with side, top stud and top posttype terminals (Figure 3) for various vehicleapplications.MT-23244Figure 3 - Types of Battery TerminalsLOW MAINTENANCE BATTERIESThese are conventionally vented lead-acid batteriesrequiring normal periodic battery maintenance.A small amount of antimony has been added to the leadto improve grid strength. The antimony tends to cause"gassing" (breaking down of water into hydrogen andoxygen gases) during battery operation, thereby loweringthe electrolyte level. Hence, periodic addition of water tothe battery cells is required."Fleetrite" and "International" low maintenance batteriesare provided with easily accessible cell filler caps.MAINTENANCE FREE BATTERIESMaintenance free batteries do not require the addition ofwater during normal service life. This is due to the factthat maintenance free batteries utilize calcium ratherthan antimony to improve grid strength. The advantageof calcium is that it greatly reduces the tendency for thebattery to gas at normal charging voltages.Consequently, very little water is used.Maintenance free batteries are not sealed. All batteries(including maintenance free) generate gases, especiallyduring charge. While the volume of gases produced bythe maintenance free battery is reduced by more than75%, there are small vent openings to allow this gas toescape of the battery is turned upside down or placed onits side"Fleetrite" and "International" maintenance free batterieshave concealed cell caps which can be removed topermit battery testing and addition of water if required.ELECTROLYTE AND SPECIFICGRAVITYThe electrolyte in a lead-acid storage battery is a dilutesulfuric acid solution. The sulfuric acid in the electrolyteis one of the necessary ingredients in the chemicalactions taking place inside the battery. It supplies thesulfate which combines with the active material of theplates. It is also the carrier for the electric current as itpasses from plate to plate. When the battery terminalsare connected to an external load, the sulfate combineswith the active materials of the positive and negativeplates forming lead sulfate and releasing electricalenergy.SPECIFIC GRAVITYSpecific gravity is a unit of measurement for determiningthe sulfuric acid content of the electrolyte. Therecommended fully charged specific gravity of most 12-volt batteries today is 1.265 corrected to 26.7oC 80°F). Abattery with a fully charged specific gravity of 1.265contains an electrolyte with approximately 36% sulfuricacid by weight or 25% by volume. The remainder of theelectrolyte is water. Pure (concentrated) sulfuric acidhas a specific gravity of 1.835. Water has beenassigned a value of 1.000. Therefore, electrolyte with aspecific gravity of 1.265 means it is 1.265 times heavierthan pure water.The state-of-charge of a battery can be determined bythe specific gravity of the electrolyte. The specific gravitycan be measured directly with a hydrometer (Figure 4).A hydrometer is a bulb-type syringe which will extractelectrolyte from the cell. A glass float in the hydrometerbarrel is calibrated to read in terms of specific gravity.The lower the float sinks in the electrolyte, the lower itsspecific gravity.MT-23245Figure 4 - Battery HydrometerFigure 5 graphically illustrates the relationship betweengravity readings and the combination of the sulfate fromthe acid with the positive and negative plates for variousstates of charge. The black dots represent the sulfateradical. A fully charged battery has all of the sulfate inthe acid. As the battery discharges, some of the sulfatebegins to appear on the plates. The acid becomes moredilute and its specific gravity drops as water replacessome of the sulfuric acid. A fully discharged battery hasCTS-4111B - Page 5
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